Classes by joshi sir
cont: 8410108680
CLASS- X
06-August-2021
TEXT-1
Indicators: Indicators are substances which indicate the acidic or basic nature of the solution by the colour change.
Types of Indicator: There are many types of indicators. Some common types of indicators are:
1. Natural Indicators: Indicators obtained from natural sources are called Natural Indicators. Litmus, turmeric, red cabbage, China rose, etc., are some common natural indicators used widely to show the acidic or basic character of substances.
Litmus: Litmus is obtained from lichens. The solution of litmus is purple in colour. Litmus paper comes in two colours- blue and red.
An acid turns blue litmus paper red.
A base turns red litmus paper blue.
Turmeric: Turmeric is another natural indicator. Turmeric is yellow in colour. Turmeric solution or paper turns reddish brown with base. Turmeric does not change colour with acid.
Red Cabbage: The juice of red cabbage is originally purple in colour. Juice of red cabbage turns reddish with acid and turns greenish with base.
2. Olfactory Indicator: Substances which change their smell when mixed with acid or base are known as Olfactory Indicators. For example; Onion, vanilla etc.
Onion: Paste or juice of onion loses its smell when added with base. It does not change its smell with acid.
Vanilla: The smell of vanilla vanishes with base, but its smell does not vanish with an acid.
Olfactory Indicators are used to ensure the participation of visually impaired students in the laboratory.
3. Synthetic Indicator: Indicators that are synthesized in the laboratory are known as Synthetic Indicators. For example; Phenolphthalein, methyl orange, etc.
Phenolphthalein is a colourless liquid. It remains colourless with acid but turns into pink with a base.
Methyl orange is originally orange in colour. It turns into the red with acid and turns into yellow with base.
| Indicator | Original Colour | Acid | Base |
| Red litmus | Red | No Change | Blue |
| Blue litmus | Blue | Red | No change |
| Turmeric | Yellow | No Change | Reddish brown |
| Red cabbage juice | Purple | Reddish | Greenish yellow |
| Phenolphthalein | Colourless | Colourless | Pink |
| Methyl Orange | Orange | Red | Yellow |
| Onion | n/a | No change | Smell vanishes |
| Vanilla | n/a | No change | Smell vanishes |
TEXT-2
Acids: Acids are sour in taste, turn blue litmus red, and dissolve in water to release H+ ions.
Example: Sulphuric acid (H2SO4), Acetic Acid (CH3COOH), Nitric Acid (HNO3) etc.
Properties of Acids:
- Acids have a sour taste.
- Turns blue litmus red.
- Acid solution conducts electricity.
- Release H+ ions in aqueous solution.
Types of Acids: Acids are divided into two types on the basis of their occurrence i.e., Natural acids and Mineral acids.
(i) Natural Acids: Acids which are obtained from natural sources are called Natural Acids or Organic Acids.
Examples:
Methanoic acid (HCOOH)
Acetic acid (CH3COOH)
Oxalic acid (C2H2O4) etc.
Example:
Hydrochloric acid (HCl)
Sulphuric acid (H2SO4)
Nitric acid (HNO3)
Carbonic acid (H2CO3)
Phosphoric acid (H3PO4) etc.
Chemical Properties of Acid:
(i) Reaction of acids with metal: Acids give hydrogen gas along with respective salt when they react with a metal.
Metal + Acid → Salt + Hydrogen
Examples:
Hydrogen gas and zinc chloride are formed when hydrochloric acid reacts with zinc metal.
Hydrogen gas and sodium sulphate are formed when sulphuric acid reacts with sodium metal.
Test For Hydrogen Gas: The gas evolved after reaction of acid with metal can be tested by bringing a lighted candle near it. If the gas bums with a pop sound, then it confirms the evolution of hydrogen gas. Burning with pop sound is the characteristic test for hydrogen gas.
(ii) Reaction of acids with metal carbonate: Acids give carbon dioxide gas and respective salts along with water when they react with metal carbonates.
Metal carbonate + Acid → Salt + Carbon dioxide + Water
Examples:
Hydrochloric acid gives carbon dioxide gas, sodium chloride along with water when reacts with sodium carbonate.
Sulphuric acid gives calcium sulphate, carbon dioxide gas, calcium sulphate and water when it reacts with calcium carbonate
Nitric acid gives sodium nitrate, water and carbon dioxide gas when it reacts with sodium carbonate.
(iii) Reaction of acid with hydrogen carbonates (bicarbonates): Acids give carbon dioxide gas, respective salt and water when they react with metal hydrogen carbonate.
Acid + Metal hydrogen carbonate → Salt + Carbon dioxide + Water
Example:
Sulphuric acid gives sodium sulphate, Carbon dioxide gas and water when it reacts with sodium bicarbonate.
Test For Evolution of Carbon Dioxide Gas: Carbon dioxide turns lime water milky when passed through it. This is the characteristic test for carbon dioxide gas.
The gas evolved because of reaction of the acid with metal carbonate or metal hydrogen carbonate turns lime water milky. This shows that the gas is carbon dioxide gas. This happens because of the formation of a white precipitate of calcium carbonate.
But when excess of carbon dioxide is passed through lime water, it makes milky colour of lime water disappear. This happens because of formation of calcium hydrogen carbonate. As calcium hydrogen carbonate is soluble in water, thus, the milky colour of solution mixture disappears.
Common in Acids: Acids give hydrogen gas when they react with metal. This shows that all acids contains hydrogen. For example; Hydrochloric acid (HCl), sulphuric acid (H2SO4), nitric acid (HNO3), etc.
When an acid is dissolved in water, it dissociates hydrogen. The dissociation of hydrogen ion in aqueous solution is the common property in all acids. Because of the dissociation of hydrogen ion in aqueous solution, an acid shows acidic behaviour.
Examples:
Hydrochloric acid (HCl) gives hydrogen ion (H+) and chloride ion (Cl–) when it is dissolved in water.
Acetic acid (CH3COOH) gives acetate ion (CH3COO–) and hydrogen ion (H+).
TEXT-3
Bases: Bases are bitter in taste, have soapy touch, turn red litmus blue and give hydroxide ions (OH–) in aqueous solution.
Examples: Sodium hydroxide (caustic soda) – NaOH
Calcium hydroxide – Ca(OH)2
Potassium hydroxide (caustic potash) – (KOH)
Properties of Bases:
- Have a bitter taste.
- Soapy to touch.
- Turns red litmus blue.
- Conducts electricity in solution.
- Release OH– ions in Aqueous Solution
Types of bases: Bases can be divided in two types – Water soluble and Water-insoluble.
The hydroxide of alkali and alkaline earth metals are soluble in water. These are also known as alkali.
For example; sodium hydroxide, magnesium hydroxide, calcium hydroxide, etc. Alkali is considered a strong base.
Chemical properties of bases:
(i) Reaction of Base with Metals: When alkali (base) reacts with metal, it produces salt and hydrogen gas.
Alkali + Metal → Salt + Hydrogen
Examples: Sodium hydroxide gives hydrogen gas and sodium zincate when reacts with zinc metal.
Sodium aluminate and hydrogen gas are formed when sodium hydroxide reacts with aluminium metal.
(ii) Reaction of Base with Oxides of Non-metals: Non-metal oxides are acidic in nature. For example; carbon dioxide is a non-metal oxide. When carbon dioxide is dissolved in water it produces carbonic acid.
Therefore, when a base reacts with non-metal oxide, both neutralize each other resulting respective salt and water.
Base + Non-metal oxide → Salt + Water
(Non-metal oxides are acidic in nature)
Examples:
Sodium hydroxide gives sodium carbonate and water when it reacts with carbon dioxide.
Calcium hydroxide gives calcium carbonate and water when it reacts with carbon dioxide.
(iii) Neutralisation Reaction: An acid neutralizes a base when they react with each other and respective salt and water are formed.
Acid + Base → Salt + Water
Since, the reaction between acid and base both neutralize each other, hence, it is also known as Neutralization Reaction.
Examples: Sodium chloride and water are formed when hydrochloric acid reacts with sodium hydroxide (a strong base).
In a similar way, calcium chloride is formed along with water when hydrochloric acid reacts with calcium hydroxide (a base).
(iv) Reaction of Acid with Metal Oxides: Metal oxides are basic in nature. Thus, when an acid reacts with a metal oxide both neutralize each other. In this reaction, the respective salt and water are formed.
Acid + Metal Oxide → Salt + Water
(Metal oxides are basic in nature)
Examples:
Calcium is a metal, thus, calcium oxide is a metallic oxide which is basic in nature. When an acid, such as hydrochloric acid, reacts with calcium oxide, neutralization reaction takes place and calcium chloride, along with water is formed.
Similarly, when sulphuric acid reacts with zinc oxide, zinc sulphate and water are formed.
Common in all bases: A base dissociates hydroxide ion in water, which is responsible for the basic behaviour of a compound.
Example: When sodium hydroxide is dissolved in water, it dissociates hydroxide ion and sodium ion.
Similarly, when potassium hydroxide is dissolved in water, it dissociates hydroxide ion and potassium ion.
Thus, the base shows its basic character because of dissociation of hydroxide ion.
Neutralisation Reaction: When an acid reacts with a base, the hydrogen ion of acid combines with the hydroxide ion of base and forms water. As these ions combine together and form water instead of remaining free, thus, both neutralize each other.
Example: When sodium hydroxide (a base) reacts with hydrochloric acid, sodium hydroxide breaks into a sodium ion and hydroxide ion and hydrochloric acid breaks into hydrogen ion and chloride ion.
Hydrogen ion and hydroxide ion combine together and form water, while sodium ion and chloride ion combine together and form sodium chloride.
Dilution of Acid and Base: The concentration of hydrogen ion in an acid and hydroxide ion in a base, per unit volume, shows the concentration of acid or base.
By mixing of acid to water, the concentration of hydrogen ion per unit volume decreases. Similarly, by addition of base to water, the concentration of hydroxide ion per unit volume decreases. This process of addition of acid or base to water is called Dilution and the acid or base is called Diluted.
The dilution of acid or base is exothermic. Thus, acid or base is always added to water and water is never added to acid or base. If water is added to a concentrated acid or base, a lot of heat is generated, which may cause splashing out of acid or base and may cause severe damage as concentrated acid and base are highly corrosive.